LiFePO4水热合成及性能研究

被引:18
作者
张静
刘素琴
黄可龙
赵裕鑫
机构
[1] hesis国家自然科学基金资助项目(No.20373010
[2] 20473017)O614.411CNKI:SUN:WJHX.0.2005-03-005南京大学化学系,生命分析化学教育部重点实验室ぱг汗δ懿牧匣а芯克?长沙410083,长沙410083,长沙410083,长沙410083
基金
高等学校博士学科点专项科研基金;
关键词
锂离子电池; 正极材料; LiFePO4;
D O I
暂无
中图分类号
O614.111 [锂Li]; TM912 [蓄电池];
学科分类号
070301 ; 081704 ; 0808 ;
摘要
Pure olive-type phased LiFePO4 powders were successfully synthesized b y hydrothermal processes. The samples were investigated by X-ray diffraction, sc anning electron microscopy and so on. Results showed that hydrothermal product w ere of pure olive-type phase with a relatively smaller particle size and regular er morphology compared with the products prepared by solid-state reaction and ba ll milling activation approaches. Charge/discharge curves at 0.5 C rate revealed that the hydrothermal products had a first discharge capacity of 124 mAh·g-1, and the capacity fading rate was only 10.7% after 50 cycles.
引用
收藏
页码:433 / 436
页数:4
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