Additions of malononitrile radicals to alkenes under mild conditions using 2,2'-azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70) as an initiator

被引:63
作者
Kita, Y [1 ]
Sano, A [1 ]
Yamaguchi, T [1 ]
Oka, M [1 ]
Gotanda, K [1 ]
Matsugi, M [1 ]
机构
[1] WAKO PURE CHEM IND LTD,TOKYO RES LABS,KAWAGOE,SAITAMA 35011,JAPAN
关键词
ANNULATION REACTIONS;
D O I
10.1016/S0040-4039(97)00700-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The attributes of 2,2'-azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70), which is an effective radical initiator at low temperature, in contrast to 2,2'-azobisisobutyronitrile (AIBN) are described. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3549 / 3552
页数:4
相关论文
共 17 条
[1]  
BARTELS HM, 1981, LIEBIGS ANN CHEM, P40
[2]   FREE-RADICAL ADDITIONS .10. SIMPLE SYNTHESES OF SOME SPIRO[2.4]HEPTANE-4,4,7,7-TETRACARBONITRILES [J].
BARTELS, HM ;
BOLDT, P ;
SCHOMBURG, D .
CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (12) :3997-4004
[3]   1.1-DICYAN-CYCLOPROPANE [J].
BOLDT, P ;
SCHULZ, L ;
ETZEMULL.J .
CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (04) :1281-&
[4]   RADICAL ADDITIONS .3. GAMMA-LACTONES FROM ALKENES [J].
BOLDT, P ;
THIELECK.W ;
ETZEMULL.J .
CHEMISCHE BERICHTE-RECUEIL, 1969, 102 (12) :4157-&
[5]  
BOLDT P, 1966, TETRAHEDRON LETT, P1415
[6]  
BOLDT P, 1970, TETRAHEDRON, P3591
[7]   RADICAL ANNULATION REACTIONS OF ALLYL IODOMALONONITRILES [J].
CURRAN, DP ;
SEONG, CM .
TETRAHEDRON, 1992, 48 (11) :2175-2190
[8]   ADDITIONS OF MALONONITRILE RADICALS TO ALKENES - NEW EXAMPLES OF 1,2-ASYMMETRIC INDUCTION IN IODINE AND PHENYLSELENIUM TRANSFER-REACTIONS [J].
CURRAN, DP ;
THOMA, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (11) :4436-4437
[9]   ATOM TRANSFER ADDITION AND ANNULATION REACTIONS OF PROPARGYL IODOMALONONITRILE [J].
CURRAN, DP ;
SEONG, CM .
TETRAHEDRON, 1992, 48 (11) :2157-2174
[10]  
KATSURA T, 1994, Patent No. 289079