SN1 reactions with inverse rate profiles

被引：45

作者：

Denegri, B

Minegishi, S

Kronja, O

Mayr, H

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

[2] Univ Zagreb, Fac Pharm & Biochem, Zagreb 10000, Croatia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 17期

关键词：

carbocations; kinetics; linear free energy relationships; nucleophilic substitution; reaction mechanisms; solvent effects;

D O I：

10.1002/anie.200353468

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbocations may accumulate during solvolysis reactions! The fact that fast ionization followed by slow trapping of the carbocation R+ is a characteristic pattern of many solvolysis reactions requires that the generally accepted energy profiles of these reactions be revised.

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页码：2302 / 2305

页数：4

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