Self-supported paired electrosynthesis using a microflow reactor without intentionally added electrolyte

被引：44

作者：

Amemiya, Fumihiro ^{[1
]}

Horii, Daisuke ^{[1
]}

Fuchigami, Toshio ^{[1
]}

Atobe, Mahito ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Yokohama, Kanagawa 2268502, Japan

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2008年 / 155卷 / 11期

关键词：

D O I：

10.1149/1.2975823

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We have developed a paired electrosynthetic system using a microflow reactor. This system enables paired electrochemical reactions composed of chloride reduction/alcohol oxidation combination to progress without intentionally added electrolyte. In addition, the use of parallel laminar flow in the microflow reactor resulted in a further improvement of the desired product yields in the paired electrosynthesis. (C) 2008 The Electrochemical Society.

引用

页码：E162 / E165

页数：4

共 18 条

[1] Origins, current status, and future challenges of green chemistry [J].

Anastas, PT ;

Kirchhoff, MM .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694

[2] PAIRED ELECTRO-ORGANIC SYNTHESES .1. CATHODIC ADIPATE WITH ANODIC BIMALONATE [J].

BAIZER, MM ;

HALLCHER, RC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (06) :809-813

[3] Building up an electrocatalytic activity scale of cathode materials for organic halide reductions [J].

Bellomunno, C ;

Bonanomi, D ;

Falciola, L ;

Longhi, M ;

Mussini, PR ;

Doubova, LM ;

Di Silvestro, G .

ELECTROCHIMICA ACTA, 2005, 50 (11) :2331-2341

[4] ELECTRODE MATERIALS FOR ELECTROSYNTHESIS [J].

COUPER, AM ;

PLETCHER, D ;

WALSH, FC .

CHEMICAL REVIEWS, 1990, 90 (05) :837-865

[5] Electrochemical Oxidation of Toluene on Glassy Carbon Electrodes in Organic Medium [J].

D'Elia, Luis F. ;

Ortiz, R. .

PORTUGALIAE ELECTROCHIMICA ACTA, 2005, 23 (04) :481-490

[6] Microflow electroorganic synthesis without supporting electrolyte [J].

Horcajada, R ;

Okajima, M ;

Suga, S ;

Yoshida, J .

CHEMICAL COMMUNICATIONS, 2005, (10) :1303-1305

[7] Self-supported paired electrosynthesis of 2,5-dimethoxy-2,5-dihydrofuran using a thin layer flow cell without intentionally added supporting electrolyte [J].

Horii, D ;

Atobe, M ;

Fuchigami, T ;

Marken, F .

ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (01) :35-39

[8] A new approach to anodic substitution reaction using parallel laminar flow in a micro-flow reactor [J].

Horii, Daisuke ;

Fuchigami, Toshio ;

Atobe, Mahito .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (38) :11692-+

[9] Self-supported methoxylation and acetoxylation electrosynthesis using a simple thin-layer flow cell [J].

Horii, Daisuke ;

Atobe, Mahito ;

Fuchigami, Toshio ;

Marken, Frank .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (08) :D143-D147

[10] Silver nanoparticles deposited on glassy carbon. Electrocatalytic activity for reduction of benzyl chloride [J].

Isse, Abdirisak A. ;

Gottardello, Silvia ;

Maccato, Chiara ;

Gennaro, Armando .

ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (11) :1707-1712

← 1 2 →