Novel structural forms for imidoamides and oxoalkoxides of bismuth

被引：27

作者：

James, SC ^{[1
]}

Norman, NC ^{[1
]}

Orpen, AG ^{[1
]}

Quayle, MJ ^{[1
]}

Weckenmann, U ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 22期

关键词：

D O I：

10.1039/dt9960004159

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between BiCl3 and 3 equivalents of Li[NHR] (R = 2,6-Me(2)C(6)H(3)) afforded the trinuclear bismuth imidoamide species [Bi-3(mu-NR)(4)(NHR)] whilst BiPh(3) and 3 equivalents of the alcohol HOR' (R' = 2,6-Cl2C6H3) gave the hexanuclear oxoalkoxide compound [Bi-6(mu(3)-O)(3)-(mu-OR)(7)(OR)(5)] both of which have been characterised by X-ray crystallography.

引用

收藏

页码：4159 / 4161

页数：3

相关论文

共 17 条

[1] Synthesis and structures of Sb[N(H)(C(6)H(2)(t)Bu(3))](3) and Bi[N(H)(C(6)H(2)(t)Bu(3))](3): Implications for the steric limits of supermesityl substitution [J].

Burford, N ;

Macdonald, CLB ;

Robertson, KN ;

Cameron, TS .

INORGANIC CHEMISTRY, 1996, 35 (13) :4013-4016

[2] STRUCTURAL STUDIES ON ARYL BISMUTH HALIDES AND HALOGENOANIONS .4. NEUTRAL LEWIS BASE ADDUCTS OF ARYL BISMUTH DIBROMIDE AND DIARYL BISMUTH BROMIDE COMPOUNDS [J].

CARMALT, CJ ;

COWLEY, AH ;

DECKEN, A ;

NORMAN, NC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 496 (01) :59-67

[3]

CARMALT CJ, 1995, IN PRESS INORG SYNTH, V31

[4] Recent developments of molecular chemistry for sol-gel processes [J].

Corriu, RJP ;

Leclercq, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (13-14) :1420-1436

[5] Synthesis and structure of [Bi-2(N(t)Bu)(4)]Li-2(2)center dot 2THF; A bimetallic cubane fragment containing a [Bi-2(N(t)Bu)(4)](2-) anion [J].

Edwards, AJ ;

Beswick, MA ;

Galsworthy, JR ;

Paver, MA ;

Raithby, PR ;

Rennie, MA ;

Russell, CA ;

Verhorevoort, KL ;

Wright, DS .

INORGANICA CHIMICA ACTA, 1996, 248 (01) :9-14

[6] INTRAMOLECULAR VERSUS INTERMOLECULAR BONDING IN AMIDOANTIMONY DIMERS - SYNTHESES AND STRUCTURES OF (SB(NME(2))[MU-N(MPY)])(2) (MPY=4-METHYLPYRIDIN-2 YL) AND [SB(NME(2))(MU-N[C6H2(OME)(3)-3,4,5])](2) [J].

EDWARDS, AJ ;

PAVER, MA ;

RENNIE, MA ;

RAITHBY, PR ;

RUSSELL, CA ;

WRIGHT, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (20) :2963-2966

[7] SELECTIVE OXIDATION AND AMMOXIDATION OF PROPYLENE BY HETEROGENEOUS CATALYSIS [J].

GRASSELLI, RK ;

BURRINGTON, JD .

ADVANCES IN CATALYSIS, 1981, 30 :133-163

[8] SELECTIVE OXIDATION AND AMMOXIDATION OF OLEFINS BY HETEROGENEOUS CATALYSIS [J].

GRASSELLI, RK .

JOURNAL OF CHEMICAL EDUCATION, 1986, 63 (03) :216-221

[9] VOLATILE METAL ALKOXIDES ACCORDING TO THE CONCEPT OF DONOR FUNCTIONALIZATION [J].

HERRMANN, WA ;

HUBER, NW ;

RUNTE, O .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (20) :2187-2206

[10]

JAMES SC, UNPUB