CsMoO2(HO3P-CH2-PO3):: a new metallodiphosphonate with a hybrid framework

被引:6
作者
Barthelet, K [1 ]
Riou, D [1 ]
Férey, G [1 ]
机构
[1] Univ Versailles, Inst Lavoisier, CNRS, UMR 8637, F-78035 Versailles, France
关键词
Metallodiphosphonates;
D O I
10.1107/S0108270102003992
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Crystals of caesium molybdenomethylenediphosphonate, [CsMoO2(CH3O6P2)], were hydrothermally synthesized at 473 K. The monoclinic structure, as determined from single-crystal X-ray diffraction, is two-dimensional and consists of stacked mixed layers of corner-sharing tetrahedral diphosphonate group sand MoO6 octahedra, between which Cs+ cations are intercalated.
引用
收藏
页码:M264 / M265
页数:2
相关论文
共 12 条
[1]  
BLESSING RH, 1995, ACTA CRSYT A, V51, P3
[2]   Structural variability of the vanadium-organodiphosphonate system: Hydrothermal syntheses and structural characterizations of one-dimensional, two-dimensional, and three-dimensional phases [J].
Bonavia, G ;
Haushalter, RC ;
OConnor, CJ ;
Zubieta, J .
INORGANIC CHEMISTRY, 1996, 35 (19) :5603-5612
[3]  
BRANDENBURG K, 1999, DIAMOND RELEASE 2 1C
[4]  
Bruker, 1997, SMART
[5]   Recent advances in metal phosphonate chemistry [J].
Clearfield, A .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (02) :268-278
[6]   BOND-VALENCE PARAMETERS FOR ANION ANION BONDS IN SOLIDS [J].
OKEEFFE, M ;
BRESE, NE .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1992, 48 :152-154
[7]   STRUCTURE OF A DIPHOSPHATE OF TRIVALENT MOLYBDENUM, RBMOP2O7 [J].
RIOU, D ;
LECLAIRE, A ;
GRANDIN, A ;
RAVEAU, B .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :989-991
[8]   Hybrid open-frameworks:: synthesis and structures of four vanado-alkyldiphosphonates with occluded potassium cations [J].
Riou, D ;
Baltazar, P ;
Férey, G .
SOLID STATE SCIENCES, 2000, 2 (01) :127-134
[9]   REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].
SHANNON, RD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767
[10]   PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].
SHELDRICK, GM .
ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473