Chiral rhodium complexes as catalysts in Diels-Alder reactions

被引：64

作者：

Carmona, D

Cativiela, C

GarciaCorreas, R

Lahoz, FJ

Lamata, MP

Lopez, JA

deViu, MPLR

Oro, LA

SanJose, E

Viguri, F

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,FAC CIENCIAS,DEPT QUIM ORGAN,E-50009 ZARAGOZA,SPAIN

[2] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,ESCUELA INGN TECN IND,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 10期

关键词：

D O I：

10.1039/cc9960001247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first rhodium enantioselective catalysts for the Diels-Alder reaction between methacrolein and cyclopentadiene are described; the molecular structure of the catalyst precursor [(eta(5)-C(5)Me(5))Rh(R-Prophos) (H2O)] [SbF6](2) is also presented.

引用

页码：1247 / 1248

页数：2

共 19 条

[1] CHIRAL IRIDIUM(III) ALPHA-AMINO ACIDATO COMPLEXES (RIR,SN,SC)-[(ETA-5-C5ME5)IR(L-PROLINATE)(CC-CME3)] AND (SIR,SN,SC)-[(ETA-5-C5ME5)IR(L-PROLINATE)(CC-CME3)] [J].

CARMONA, D ;

LAHOZ, FJ ;

ATENCIO, R ;

ORO, LA ;

LAMATA, MP ;

JOSE, ES .

TETRAHEDRON-ASYMMETRY, 1993, 4 (07) :1425-1428

[2] OPTICALLY-ACTIVE PSEUDOCTAHEDRAL RHODIUM(III), IRIDIUM(III), AND RUTHENIUM(II) COMPLEXES WITH ALPHA-AMINO ACIDATO LIGANDS - CRYSTAL-STRUCTURES OF RIRSCSN-[(C5ME5)IR(PRO)CL].1/2H2O AND SIRSCSN-[(C5ME5)IR(PRO)CL].1/2H2O (HPRO = L-PROLINE) [J].

CARMONA, D ;

MENDOZA, A ;

LAHOZ, FJ ;

ORO, LA ;

LAMATA, MP ;

JOSE, ES .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 396 (01) :C17-C21

[3] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[4]

DICKSON RS, 1985, HOMOGENEOUS CATALYSI

[5] C-2-SYMMETRIC CATIONIC COPPER(II) COMPLEXES AS CHIRAL LEWIS-ACIDS - COUNTERION EFFECTS IN THE ENANTIOSELECTIVE DIELS-ALDER REACTION [J].

EVANS, DA ;

MURRY, JA ;

VONMATT, P ;

NORCROSS, RD ;

MILLER, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :798-800

[6] CHIRAL (ACYLOXY)BORANE (CAB) - A POWERFUL AND PRACTICAL CATALYST FOR ASYMMETRIC DIELS-ALDER REACTIONS [J].

FURUTA, K ;

SHIMIZU, S ;

MIWA, Y ;

YAMAMOTO, H .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (07) :1481-1483

[7] ASYMMETRIC INDUCTION IN THE DIELS-ALDER REACTION CATALYZED BY CHIRAL METALLOCENE TRIFLATE COMPLEXES - DRAMATIC EFFECT OF SOLVENT POLARITY [J].

JAQUITH, JB ;

GUAN, JY ;

WANG, ST ;

COLLINS, S .

ORGANOMETALLICS, 1995, 14 (03) :1079-1081

[8] CATALYTIC ASYMMETRIC DIELS-ALDER REACTIONS [J].

KAGAN, HB ;

RIANT, O .

CHEMICAL REVIEWS, 1992, 92 (05) :1007-1019

[9] LANTHANIDE(III)-CATALYZED ENANTIOSELECTIVE DIELS-ALDER REACTIONS - STEREOSELECTIVE SYNTHESIS OF BOTH ENANTIOMERS BY USING A SINGLE CHIRAL SOURCE AND A CHOICE OF ACHIRAL LIGANDS [J].

KOBAYASHI, S ;

ISHITANI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) :4083-4084

[10]

KUNDIG EP, 1994, ANGEW CHEM INT EDIT, V33, P1856, DOI 10.1002/anie.199418561

← 1 2 →