Synthesis of triisopropyl alpha-(trimethylsilyloxy)propargyl stannanes

被引：3

作者：

Cunico, RF

机构：

[1] Department of Chemistry, Northern Illinois University, DeKalb

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 04期

关键词：

D O I：

10.1016/0040-4039(95)02212-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acetyl(triisopropyl)stannane reacts with alkynyllithium reagents predominantly by way of carbonyl addition to give the title compounds after in situ trimethylsilylation.

引用

页码：437 / 438

页数：2

共 16 条

[1] ALLENE TRANSFER-REACTIONS - A NEW SYNTHESIS OF TERMINAL ALLENES [J].

BALDWIN, JE ;

ADLINGTON, RM ;

BASAK, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) :1284-1285

[2] THE TRIISOPROPYLSILYL GROUP AS A HYDROXYL-PROTECTING FUNCTION [J].

CUNICO, RF ;

BEDELL, L .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (23) :4797-4798

[3] REMARKABLE INCREASE IN THE DIASTEREOFACIAL SELECTIVITY OF THE ADDITION OF BETA-METHYL ALPHA-(ALKOXY)ALLYLSTANNANE TO ALDEHYDES - SUBSTITUENT EFFECTS ON DIASTEREOFACIAL SELECTIVITY [J].

GUNG, BW ;

SMITH, DT ;

WOLF, MA .

TETRAHEDRON LETTERS, 1991, 32 (01) :13-16

[4] CONDENSATION REACTION OF TIN PROPARGYLIC DERIVATIVES AND TIN ALLENIC DERIVATIVES ON CHLORAL - KINETIC STUDY [J].

LEQUAN, M ;

GUILLERM, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 54 (JUN16) :153-164

[5] SYNTHESIS OF ANTI-HOMOALLYLIC ALCOHOLS AND MONOPROTECTED 1,2-DIOLS THROUGH INCL3-PROMOTED ADDITION OF ALLYLIC STANNANES TO ALDEHYDES [J].

MARSHALL, JA ;

HINKLE, KW .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (07) :1920-1921

[6] SYNTHESIS OF ALKOXY-SUBSTITUTED ALLENYLSTANNANE AND PROPARGYLSTANNANE REAGENTS FROM CARBENE COMPLEXES [J].

MERLIC, CA ;

ALBANEZE, J .

TETRAHEDRON LETTERS, 1995, 36 (07) :1011-1014

[7] SOME FURTHER-STUDIES ON ACYLTRIMETHYLSTANNANES [J].

MITCHELL, TN ;

KWETKAT, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 439 (02) :127-138

[8] A CONVENIENT SYNTHESIS OF ALPHA-HYDROXYALLENES BY THE REACTION OF PROPARGYL IODIDES WITH ALDEHYDES IN THE PRESENCE OF STANNOUS HALIDE [J].

MUKAIYAMA, T ;

HARADA, T .

CHEMISTRY LETTERS, 1981, (05) :621-624

[9] PREPARATION AND PROPERTIES OF ALPHA-TIN KETONES [J].

PEDDLE, GJD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 14 (01) :139-&

[10] STEREOSELECTIVE THERMAL-REACTIONS BETWEEN (E)-1-ALKOXYMETHOXYBUT-2-ENYL-(TRIBUTYL)STANNANES AND ALDEHYDES [J].

PRATT, AJ ;

THOMAS, EJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (08) :1521-1527

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