Adsorption structure of 1,3-butadiene on Pd(110)

被引：22

作者：

Katano, S

Ichihara, S

Ogasawara, H

Kato, HS

Komeda, T

Kawai, M

Domen, K

机构：

[1] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

SURFACE SCIENCE | 2002年 / 502卷

关键词：

electron energy loss spectroscopy (EELS); near edge extended X-ray absorption fine structure (NEXAFS); scanning tunneling microscopy; palladium; chemisorption; adsorption kinetics;

D O I：

10.1016/S0039-6028(01)01928-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption structure of 1,3-butadiene chemisorbed on Pd(110) has been studied by high resolution electron energy loss spectroscopy (HREELS). near edge X-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The HREELS and NEXAFS results revealed that 1,3-butadiene is adsorbed with pi-bond and the molecular plane is parallel to the surface, in which the C-C single bond in 1,3-butadiene on Pd(110) is aligned toward [1 (1) over bar0]. The adsorption site and geometry were determined oil the basis of the STM image analysis. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：164 / 168

页数：5

共 19 条

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