Ketone-directed peracid epoxidation of cyclic alkenes

被引：12

作者：

Armstrong, A

Barsanti, PA

Clarke, PA

Wood, A

机构：

[1] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND

[2] PFIZER LTD,CENT RES,DISCOVERY CHEM,SANDWICH CT13 9NJ,KENT,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 12期

关键词：

D O I：

10.1039/p19960001373

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketone carbonyl groups are shown to direct the peracid epoxidation of cyclic alkenes with greater selectivity than that displayed by esters. An O-18 labelling study is used to show that a dioxirane intermediate is not involved in these reactions.

引用

页码：1373 / 1380

页数：8

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