Quadratic nonlinear optical properties of correlated chromophores: Cyclic 6,6'-dinitro-1,1'-binaphthyl-2,2'-ethers

被引：42

作者：

Hendrickx, E ^{[1
]}

Boutton, C ^{[1
]}

Clays, K ^{[1
]}

Persoons, A ^{[1
]}

vanEs, S ^{[1
]}

Biemans, T ^{[1
]}

Meijer, B ^{[1
]}

机构：

[1] EINDHOVEN UNIV TECHNOL,ORGAN CHEM LAB,NL-5600 MB EINDHOVEN,NETHERLANDS

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 270卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(97)00325-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first hyperpolarizability, beta, of a series of cyclic 6,6'-dinitro-1,1'-binaphthyl-2,2'-ethers has been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic-generation and compared with the absorption data and semi-empirical calculations. The results show the critical dependence of beta on the conformation of the alkoxy donor and the dihedral angle of the binaphthyl unit.

引用

页码：241 / 244

页数：4

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