Steam reforming of methane in a membrane reactor: An industrial case study

被引:67
作者
Gallucci, F
Comite, A
Capannelli, G
Basile, A
机构
[1] Univ Calabria, CNR, ITM, I-87030 Commenda Di Rende, Italy
[2] Univ Genoa, Dipartimento Chim & Chim Ind, I-16146 Genoa, Italy
关键词
D O I
10.1021/ie058063j
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The methane steam-reforming reaction has been investigated from a modeling point of view, considering the effect of different parameters on methane conversion. In particular, we point our attention mainly toward the influence of the different retentate and permeate flux configurations on both methane conversion and hydrogen recovery. Both methane conversion and hydrogen recovery are higher in the membrane reactor operated in the countercurrent mode than in the cocurrent mode. A comparison between a traditional steam-reforming process and a membrane reactor process has also been made. The use of a membrane reactor can simplify the process scheme, and the operating temperature and the fuel consumption are lower than those of a traditional system.
引用
收藏
页码:2994 / 3000
页数:7
相关论文
共 11 条
[1]   PROMOTION OF METHANE STEAM REFORMING USING RUTHENIUM-DISPERSED MICROPOROUS ALUMINA MEMBRANE REACTOR [J].
CHAI, M ;
MACHIDA, M ;
EGUCHI, K ;
ARAI, H .
CHEMISTRY LETTERS, 1993, (01) :41-44
[2]   Laboratory reactors [J].
Forni, L .
CATALYSIS TODAY, 1997, 34 (3-4) :353-367
[3]   Experimental study of the methane steam reforming reaction in a dense Pd/Ag membrane reactor [J].
Gallucci, F ;
Paturzo, L ;
Famà, A ;
Basile, A .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (04) :928-933
[4]   A simulation study of the steam reforming of methane in a dense tubular membrane reactor [J].
Gallucci, F ;
Paturzo, L ;
Basile, A .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (06) :611-617
[5]   Novel riser simulator for methane reforming using high temperature membranes [J].
Jarosch, K ;
de Lasa, HI .
CHEMICAL ENGINEERING SCIENCE, 1999, 54 (10) :1455-1460
[6]  
KIKUCHI E, 1991, STUD SURF SCI CATAL, V61, P509
[7]   Methane steam reforming in a Pd-Ru membrane reactor [J].
Nam, SW ;
Yoon, SP ;
Ha, HY ;
Hong, SA ;
Maganyuk, AP .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2000, 17 (03) :288-291
[8]   A simulative comparison of dense and microporous membrane reactors for the steam reforming of methane [J].
Oklany, JS ;
Hou, K ;
Hughes, R .
APPLIED CATALYSIS A-GENERAL, 1998, 170 (01) :13-22
[9]   METHANE STEAM REFORMING IN ASYMMETRIC PD-AG AND PD-AG/POROUS SS MEMBRANE REACTORS [J].
SHU, J ;
GRANDJEAN, BPA ;
KALIAGUINE, S .
APPLIED CATALYSIS A-GENERAL, 1994, 119 (02) :305-325
[10]  
*VCH, 1992, HYDR ULLM ENC IND A, V13, P327