Luminescent layers for enhanced silicon solar cell performance: Down-conversion

被引:545
作者
Richards, BS [1 ]
机构
[1] Univ New S Wales, Ctr Excellence Adv Silicon Photovolta & Photon, Sydney, NSW 2052, Australia
关键词
luminescence; down-conversion; quantum cutting; rare-earths; solar cells; photovoltaics;
D O I
10.1016/j.solmat.2005.07.001
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A down-converting (DC) layer placed on the front side of a silicon solar cell has the potential to generate more than one low-energy photon for every incident high-energy photon. Recent theory has predicted that DC in conjunction with a silicon solar cell can achieve a conversion efficiency of up to 38.6%. This paper examines the application of rare-earth-doped inorganic materials for achieving external quantum efficiencies greater than unity and enhancing the conversion efficiency of silicon solar cells. Such DC mechanisms have been applied in similar phosphor materials used by the lighting and display industries. The opportunities for the DC of high-energy solar photons to multiple photons with energy greater than the silicon bandgap are discussed. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1189 / 1207
页数:19
相关论文
共 55 条
[1]  
AUZEL F, 1966, CR ACAD SCI B PHYS, V262, P1016
[2]   A SURFACE RECOMBINATION MODEL APPLIED TO LARGE FEATURES IN INORGANIC PHOSPHOR EFFICIENCY MEASUREMENTS IN THE SOFT-X-RAY REGION [J].
BENITEZ, EL ;
HUSK, DE ;
SCHNATTERLY, SE ;
TARRIO, C .
JOURNAL OF APPLIED PHYSICS, 1991, 70 (06) :3256-3260
[3]   INVESTIGATION OF LUMINESCENT MATERIALS UNDER ULTRAVIOLET EXCITATION-ENERGIES FROM 5 TO 25 EV [J].
BERKOWITZ, JK ;
OLSEN, JA .
JOURNAL OF LUMINESCENCE, 1991, 50 (02) :111-121
[4]  
BOER KW, 1990, SURVEY SEMICONDUCTOR
[5]   POSSIBILITY OF LUMINESCENT QUANTUM YIELDS GREATER THAN UNITY [J].
DEXTER, DL .
PHYSICAL REVIEW, 1957, 108 (03) :630-633
[6]  
DICKE GH, 1968, SPECTRA ENERGY LEVEL
[7]   Lanthanide-sensitized lanthanide luminescence: Terbium-sensitized ytterbium luminescence in a trinuclear complex [J].
Faulkner, S ;
Pope, SJA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (35) :10526-10527
[8]   Quantum efficiency of down-conversion phosphor LiGdF4:Eu [J].
Feldmann, C ;
Jüstel, T ;
Ronda, CR ;
Wiechert, DU .
JOURNAL OF LUMINESCENCE, 2001, 92 (03) :245-254
[9]  
Friedman P., 1987, LUMINESCENT SOLAR CO
[10]   Visible and near-IR luminescence via energy transfer in rare earth doped mesoporous titania thin films with nanocrystalline walls [J].
Frindell, KL ;
Bartl, MH ;
Robinson, MR ;
Bazan, GC ;
Popitsch, A ;
Stucky, GD .
JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (01) :81-88