2 alpha,3 alpha:7 alpha,8 alpha-diepoxy-cis-himachalane

被引：11

作者：

Chiaroni, A ^{[1
]}

Riche, C ^{[1
]}

Lassaba, E ^{[1
]}

Benharref, A ^{[1
]}

机构：

[1] UNIV CADI AYYAD,FAC SCI,LAB SUBSTANCES NAT & HETEROCYCLES,SEMLALIA MARRAKECH,MOROCCO

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196008797

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereochemistry of the major isomer resulting from the epoxidation of gamma-cis-himachalene has been established as 2 alpha,3 alpha:7 alpha,8 alpha-diepoxy-gamma-cis-himachalen C15H24O2. Hence, the configurations of the two resulting derivatives have been deduced, The seven-membered ring is twist-chair shaped while the six-membered ring adopts a 1,2-diplanar conformation.

引用

页码：3240 / 3243

页数：4

共 13 条

[1]

BUCOURT R, 1965, SOC CHIM, V5, P1366

[2] 2 alpha,3 alpha:7 beta,8 beta-Diepoxy-trans-himachalane [J].

Chiaroni, A ;

Riche, C ;

Benharref, A ;

ElJamili, H ;

Lassaba, E .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :2502-2504

[3] STRUCTURE 2-ALPHA,3-ALPHA,7-ALPHA,13-ALPHA-DIEPOXYHIMACHALANE [J].

CHIARONI, A ;

RICHE, C ;

BENHARREF, A ;

CHEKROUN, A ;

LAVERGNE, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :1720-1722

[4] STRUCTURE OF 3-CHLORO-4-BETA,9-BETA-HIMACHALAN-OL-9A [J].

CHIARONI, A ;

PAIS, M ;

RICHE, C ;

BENHARREF, A ;

CHEKROUN, A ;

LAVERGNE, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :1945-1948

[5] MOLECULAR GEOMETRY .1. MACHINE COMPUTATION OF COMMON RINGS [J].

HENDRICKSON, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (22) :4537-+

[6]

JOHNSON CK, 1965, ORNL3794

[7]

Plattier M., 1974, RECHERCHES, V19, P131

[8]

PLATTIER M, 1974, RECHERCHES, V19, P145

[9]

RICHE C, 1983, R3M REPRESENTATION M

[10]

RICHE C, 1981, PHIL LOGICIEL REDUCT

← 1 2 →