Water-soluble resorcin[4]arene: Complexation of anionic aromatic guests by cooperativity of electrostatic and hydrophobic interactions

被引:36
作者
Ahn, DR [1 ]
Kim, TW [1 ]
Hong, JI [1 ]
机构
[1] Seoul Natl Univ, Dept Chem, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
noncovalent interaction; water-soluble resorcin[4]arene; cooperativity; complexation;
D O I
10.1016/S0040-4039(99)01227-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Water-soluble resorcin[4]arene based cavitand 2 was synthesized by reaction of bromomethylcavitand 1 with hexamethylenetetramine. The bowl-shaped cavitand host 2 shows a good binding affinity to anionic aromatic guests with 1:1 binding in D2O. The guest inclusion within the host cavity was confirmed by H-1 NMR spectroscopy. Electrostatic interaction as well as hydrophobic interaction turned out to cooperatively act as binding forces for a strong complex formation in water. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6045 / 6048
页数:4
相关论文
共 29 条