Novel fused-LEDs devices as optical sensors for colorimetric analysis

被引:69
作者
Lau, KT
Baldwin, S
Shepherd, RL
Dietz, PH
Yerzunis, WS
Diamond, D [1 ]
机构
[1] Dublin City Univ, Natl Ctr Sensor Res, Sch Chem Sci, Dublin 9, Ireland
[2] Mitsubishi Elect Res Labs, Cambridge Res Lab, Cambridge, MA 02139 USA
关键词
fused-LEDs; optical sensor; pH sensing; reflectance measurements; colorimetric analysis; acidochromic dyes; evanescent wave;
D O I
10.1016/j.talanta.2003.10.034
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The development of a novel, low power optical sensing platform based on light emitting diodes (LEDs) is described. The sensor is constructed from a pair of LEDs fused together at an angle where one LED functions as the light source and the other LED is reverse biased to function as a light detector. Sensor function is based on the level of light received by the detector diode, which varies with the reflectance of the interface between the device and its environment, or the chemochromic membrane that covers the device. A simple microprocessor circuit is used to measure the time taken for the photon-induced current to discharge the detector LED from an initial 5 V (logic 1) to 1.7 V (logic zero). This sensing device has been successfully used for colour and colour-based pH measurements and offers extremely high sensitivity, enabling detection down to the sub micro molar level of dyes. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:167 / 173
页数:7
相关论文
共 18 条
[1]   A FLOW-INJECTION APPROACH TO THE CONTINUOUS MONITORING OF RESIDUAL COAGULANTS (ALUMINUM AND IRON) IN POTABLE AND TREATED WATERS [J].
BENSON, RL ;
WORSFOLD, PJ .
SCIENCE OF THE TOTAL ENVIRONMENT, 1993, 135 (1-3) :17-25
[2]   High-acidity determination in salt-containing acids by optical sensors. The scope of a dual-transducer approach and the Hammett acidity function [J].
Canada, TA ;
Allain, LR ;
Beach, DB ;
Xue, ZL .
ANALYTICAL CHEMISTRY, 2002, 74 (11) :2535-2540
[3]  
EARLL M, GUIDE LOG P PK MEASU
[4]   INTEGRATED OPTICAL SENSORS BASED ON REFRACTOMETRY OF ION-SELECTIVE MEMBRANES [J].
FREINER, D ;
KUNZ, RE ;
CITTERIO, D ;
SPICHIGER, UE ;
GALE, MT .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 29 (1-3) :277-285
[5]   Package design for low-cost optical liquid-level sensors [J].
Ghosh, AK ;
Bedi, NS ;
Paul, P .
OPTICAL ENGINEERING, 2000, 39 (05) :1405-1412
[6]   A MULTIWAVELENGTH PHOTOMETER BASED ON LIGHT-EMITTING-DIODES [J].
HAUSER, PC ;
RUPASINGHE, TWT ;
CATES, NE .
TALANTA, 1995, 42 (04) :605-612
[7]  
HAUSER PC, 1993, CHIANG TALANTA, V40, P981
[8]  
Lechuga LM, 2000, QUIM ANAL, V19, P61
[9]   A simple device for quantitative colorimetric diffuse reflectance measurements [J].
Matias, FAA ;
Vila, MMDC ;
Tubino, M .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 88 (01) :60-66
[10]   Infrared optical sensors for water quality monitoring [J].
Mizaikoff, B .
WATER SCIENCE AND TECHNOLOGY, 2003, 47 (02) :35-42