High-resolution Fourier transform infrared spectroscopy and analysis of the ν3 fundamental band of P4

被引：25

作者：

Boudon, V

Mkadmi, EB

Bürger, H

Pierre, G

机构：

[1] Univ Bourgogne, Phys Lab, CNRS, F-21078 Dijon, France

[2] Berg Univ Gesamthsch Wuppertal, D-42097 Wuppertal, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 305卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(99)00348-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present the first high-resolution infrared absorption study of the nu(3) fundamental of white phosphorus, P-4. This spectrum has been analyzed using the STDS (Spherical Top Data System) software. The band center lies at 466.286 cm(-1) With the approximation (B zeta)(3) = -B-0/2, we found that the ground-state bond length is r(0) = 219.58 pm. This value is consistent with that of ab initio studies reported previously but significantly different from a value obtained from a Raman study. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：21 / 27

页数：7

共 17 条

[1]

[Anonymous], 1992, Spherical Top Spectra

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