Asymmetric hydrogenation of imines and olefins using phosphine-oxazoline iridium complexes as catalysts

被引：105

作者：

Trifonova, A ^{[1
]}

Diesen, JS ^{[1
]}

Andersson, PG ^{[1
]}

机构：

[1] Uppsala Univ, Dept Chem Organ Chem, SE-75124 Uppsala, Sweden

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 08期

关键词：

catalysis; hydrogenation; imine; iridium; olefin;

D O I：

10.1002/chem.200500942

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we describe the synthesis of a new class of chiral phosphine-oxa- zolines and their application as ligands in iridium-catalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize the results obtained is also presented.

引用

页码：2318 / 2328

页数：11

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