Enantioselective syntheses of (-)-7-oxo-kolavenic acid and (-)-methyl solidagonate from (-)-verbenone

被引：6

作者：

Kato, M ^{[1
]}

Kosugi, H ^{[1
]}

Ichiyanagi, T ^{[1
]}

Suzuki, T ^{[1
]}

Kodaira, A ^{[1
]}

Drechsel, P ^{[1
]}

Hagiwara, H ^{[1
]}

机构：

[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 29期

关键词：

natural products; asymmetric synthesis; stereocontrol; ene reactions;

D O I：

10.1016/S0040-4039(99)01030-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first enantioselective synthesis of the title neo-trans-clerodanes 3 and 4b from (-)-verbenone 5 has been accomplished using the ene reaction and stereoselective conjugate addition reaction to the enone 13 as the key step. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：5377 / 5378

页数：2

共 5 条

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[2]

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[5]

Snider B. B., COMPREHENSIVE ORGANI, V2, P527, DOI DOI 10.1016/B978-0-08-052349-1.00040-8

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