Metallacycles of the imidoylamidinato compounds HNC(R)NC(R)NH and Group 13 elements. Crystal structure of the complex [GaMe(2){HNC(CF3)NC(CF3)NH}]

被引：20

作者：

Aris, DR ^{[1
]}

Barker, J ^{[1
]}

Phillips, PR ^{[1
]}

Alcock, NW ^{[1
]}

Wallbridge, MGH ^{[1
]}

机构：

[1] ASSOCIATED OCTEL CO LTD,WIRRAL L65 4HF,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a700016b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of trimethylgallium with trifluoroacetamidine [H2NC(CF3)NH] resulted in an unusual elimination reaction, and yielded the air-stable volatile metallacycle [GaMe(2){HNC(CF3)NC(CF3)NH}] which shows a planar six-membered (GaNCNCN) ring; a related aluminium system. [AlMe(2){HNC(Ph)NC(Ph)NH}] was formed using benzamidine [H2NC(Ph)NH].

引用

页码：909 / 910

页数：2

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