Towards uranium catalysts

被引:381
作者
Fox, Alexander R. [1 ]
Bart, Suzanne C. [2 ]
Meyer, Karsten [2 ]
Cummins, Christopher C. [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany
基金
美国国家科学基金会;
关键词
D O I
10.1038/nature07372
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The forefront of research into the complexes of uranium reveals chemical transformations that challenge and expand our view of this unique element. Certain ligands form multiple bonds to uranium, and small, inert molecules such as nitrogen and carbon dioxide become reactive when in complex with the metal. Such complexes provide clues to the catalytic future of uranium, in which the applications of the element extend far beyond the nuclear industry. Most excitingly, the ability of uranium to use its outermost f electrons for binding ligands might enable the element to catalyse reactions that are impossible with conventional, transition- metal catalysts.
引用
收藏
页码:341 / 349
页数:9
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