Serendipitous assembly of polynuclear cage compounds

被引：327

作者：

Winpenny, REP ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b107118c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The idea of synthesising polynuclear cage compounds without strictly designing the final product is an extremely productive means of producing new polymetallic cages. Some of the considerations behind this approach-termed "serendipitous assembly"-are briefly reviewed, and one project is discussed in some detail to illustrate how such a programme develops. The complexes discussed involve nickel and cobalt cages, ranging as large as cages containing twenty-four metal centres. The magnetic properties of the more interesting cages, including a {Ni-12} cyclic single molecule magnet, are discussed.

引用

页码：1 / 10

页数：10

共 41 条

[1]

Atkinson IM, 1999, CHEM COMMUN, P285

[2]

BATSANOV AS, 1991, KOORDINATS KHIM+, V17, P662

[3] CRYSTAL AND MOLECULAR-STRUCTURE OF AND MAGNETIC COUPLING IN 2 COMPLEXES CONTAINING GADOLINIUM(III) AND COPPER(II) IONS [J].

BENCINI, A ;

BENELLI, C ;

CANESCHI, A ;

CARLIN, RL ;

DEI, A ;

GATTESCHI, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8128-8136

[4]

Benelli C, 1996, ANGEW CHEM INT EDIT, V35, P1825

[5] A decanuclear iron(III) single molecule magnet: Use of Monte Carlo methodology to model the magnetic properties [J].

Benelli, C ;

Cano, J ;

Journaux, Y ;

Sessoli, R ;

Solan, GA ;

Winpenny, REP .

INORGANIC CHEMISTRY, 2001, 40 (02) :188-+

[6]

Benelli C, 2000, CHEM-EUR J, V6, P883, DOI 10.1002/(SICI)1521-3765(20000303)6:5<883::AID-CHEM883>3.3.CO

[7]

2-S

[8] SYNTHESIS, STRUCTURAL CHARACTERIZATION AND STUDIES OF OCTANUCLEAR COPPER-COMPLEXES OF PYRIDONATE AND CARBOXYLATE LIGANDS [J].

BLAKE, AJ ;

GRANT, CM ;

GREGORY, CI ;

PARSONS, S ;

RAWSON, JM ;

REED, D ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (02) :163-175

[9] NEW POLYNUCLEAR NICKEL-COMPLEXES WITH A VARIETY OF PYRIDONATE AND CARBOXYLATE LIGANDS [J].

BLAKE, AJ ;

BRECHIN, EK ;

CODRON, A ;

GOULD, RO ;

GRANT, GM ;

PARSONS, S ;

RAWSON, JM ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (19) :1983-1985

[10] THE SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A CYCLIC DODECANUCLEAR NICKEL-COMPLEX [J].

BLAKE, AJ ;

GRANT, CM ;

PARSONS, S ;

RAWSON, JM ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) :2363-2364

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