Efficient removal of polymerization inhibitors by adsorption on the surface of an optimized alumina

被引:12
作者
Nédez, C
Ray, JL
机构
[1] Rhodia Chim, Dept Res & Dev, Usine Salindres, F-30340 Salindres, France
[2] Procatalyse, F-92500 Rueil Malmaison, France
关键词
D O I
10.1021/la981271e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
tert-Butylcatechol (TBC) is an efficient inhibitor of parasitic polymerization of many monomers during their transportation and storage. Just before the monomers are used, removal of the inhibitor is often necessary and can easily be achieved by adsorption on alumina, The influence of the main physical parameters of the alumina on its performance has been particularly studied. The accessibility of the TBC molecule into the internal porous network of the alumina beads or extrudates appears to be the key parameter, clearly more than the specific surface area. Procatalyse's specially optimized Spheralite 538E performs particularly well in removing TBC from hydrocarbon streams.
引用
收藏
页码:5932 / 5936
页数:5
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