Stereochemistry of macrocyclic compounds capable of catenation: X-ray crystal structure of bis(p-phenylene)-31-crown-9 ether

被引：2

作者：

Buchanan, GW

Reynolds, VM

Bensimon, C

机构：

[1] Ottawa-Carleton Chemistry Institute, Department of Chemistry, Carleton University, Ottawa, Ont.

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1996年 / 382卷 / 01期

关键词：

conformation; macrocyclic; polyether;

D O I：

10.1016/0022-2860(96)09239-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The X-ray crystal structure of the title material has been determined. The molecule possesses one O-C-C-O unit with an unusual trans geometry. The mean interplanar separation between the aromatic rings is 4.93 Angstrom and the interplanar angle is 90.40(20)degrees. The structure is compared with that found for related systems capable of catenation.

引用

页码：69 / 73

页数：5

共 5 条

[1] MOLECULAR MECCANO .2. SELF-ASSEMBLY OF [ETA]CATENANES [J].

AMABILINO, DB ;

ASHTON, PR ;

BROWN, CL ;

CORDOVA, E ;

GODINEZ, LA ;

GOODNOW, TT ;

KAIFER, AE ;

NEWTON, SP ;

PIETRASZKIEWICZ, M ;

PHILP, D ;

RAYMO, FM ;

REDER, AS ;

RUTLAND, MT ;

SLAWIN, AMZ ;

SPENCER, N ;

STODDART, JF ;

WILLIAMS, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (04) :1271-1293

[2] MOLECULAR MECCANO .1. [2]ROTAXANES AND A [2]CATENANE MADE TO ORDER [J].

ANELLI, PL ;

ASHTON, PR ;

BALLARDINI, R ;

BALZANI, V ;

DELGADO, M ;

GANDOLFI, MT ;

GOODNOW, TT ;

KAIFER, AE ;

PHILP, D ;

PIETRASZKIEWICZ, M ;

PRODI, L ;

REDDINGTON, MV ;

SLAWIN, AMZ ;

SPENCER, N ;

STODDART, JF ;

VICENT, C ;

WILLIAMS, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (01) :193-218

[3]

BOVIL MJ, 1980, J CHEM SOC P2, P1959

[4] STEREOCHEMISTRY OF NONCOVALENT INTERACTIONS IN ORGANIC AND METAL CATIONIC COMPLEXES [J].

COXON, AC ;

LAIDLER, DA ;

PETTMAN, RB ;

STODDART, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (26) :8260-8262

[5] NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].

GABE, EJ ;

LEPAGE, Y ;

CHARLAND, JP ;

LEE, FL ;

WHITE, PS .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 :384-387

← 1 →