Manganese(III) acetate and copper(II) acetate promoted oxidation of β-enaminoamides and β-enaminoesters.

被引：18

作者：

Cossy, J ^{[1
]}

Bouzide, A ^{[1
]}

机构：

[1] Ecole Super Phys & Chim Ind, CNRS, Chim Organ Lab, F-75231 Paris 05, France

来源：

TETRAHEDRON | 1999年 / 55卷 / 21期

关键词：

D O I：

10.1016/S0040-4020(99)00286-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclic enamines were oxidized by manganese acetate [Mn(OAc)(3)] and copper acetate [Cu(OAc)(2)] to produce alpha,beta-unsaturated imine, azadiene and aniline derivatives depending on the ring size. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：6483 / 6496

页数：14

共 26 条

[1]

AUDEBERT P, 1995, J ELECTROANAL CHEM, V389, P227

[2]

BOCK H, 1984, Z NATURFORSCH B, V39, P763

[3] NEW SYNTHESIS OF LACTAMS AND SPIROLACTAMS RADICAL CYCLIZATION INDUCED BY MANGANESE(III) ACETATE [J].

COSSY, J ;

LEBLANC, C .

TETRAHEDRON LETTERS, 1989, 30 (34) :4531-4534

[4]

COSSY J, 1988, SYNTHESIS-STUTTGART, P720

[5]

COSSY J, 1993, SYNLETT, P202

[6]

COSSY J, 1989, SYNTHESIS-STUTTGART, P753

[7] GENERATION OF RADICAL CATIONS FROM ENAMINES AND THEIR ADDITION TO UNACTIVATED OLEFINS [J].

COSSY, J ;

BOUZIDE, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (15) :1218-1219

[8] REGIOSELECTIVE AND STEREOSELECTIVE CYCLIZATIONS - APPLICATION TO NATURAL-PRODUCTS SYNTHESIS [J].

COSSY, J .

PURE AND APPLIED CHEMISTRY, 1992, 64 (12) :1883-1888

[9]

COSSY J, UNPUB

[10] CYCLIZATIONS OF UNSATURATED.CR(COX)2 RADICALS - MANGANESE(III) ACETATE OXIDATIVE CYCLIZATIONS OF UNSATURATED ACETOACETATES AND ATOM-TRANSFER CYCLIZATIONS OF UNSATURATED HALOACETOACETATES GIVE THE SAME RADICALS [J].

CURRAN, DP ;

MORGAN, TM ;

SCHWARTZ, CE ;

SNIDER, BB ;

DOMBROSKI, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (17) :6607-6617

← 1 2 3 →