Syntheses of diethyleneoxy bridged cryptophanes and their complexing abilities with alkali metal and alkylammonium cations

被引：11

作者：

Akabori, S ^{[1
]}

Miura, M ^{[1
]}

Takeda, M ^{[1
]}

Yuzawa, S ^{[1
]}

Habata, Y ^{[1
]}

Ishii, T ^{[1
]}

机构：

[1] TSURUMI UNIV,SCH DENT MED,TSURUMI KU,TSURUMI 230,JAPAN

来源：

SUPRAMOLECULAR CHEMISTRY | 1996年 / 7卷 / 03期

关键词：

D O I：

10.1080/10610279608027515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The anti- and syn-diethyleneoxy bridged cryptophanes (3a and 3b) were prepared by the direct trimerization of 1,5-bis[(4-hydroxymethyl)-2-methoxyphenoxy]-3-oxapentane, which was obtained by the reaction of diethyleneglycol ditosylate with vanillyl alcohol and/or by stepwise methods from vanillyl alcohol, The syn isomer (3b) showed highly selective complexing abilities for cesium, and the tetraethylammoninm and triethylmethylammonium cations among the investigated alkali metal and alkylammonium cations as compared with those of the anti isomer (3a).

引用

页码：187 / 193

页数：7

共 22 条

[1] SYNTHESES OF PHOTORESPONSIVE CYCLOBUTANE-1,2-DICARBONYL-CAPPED 2.N DIAZACROWN ETHERS BY INTRAMOLECULAR [2 + 2]PHOTOCYCLOADDITION AND THE STRUCTURES OF THEIR LITHIUM AND MERCURY(II) COMPLEXES [J].

AKABORI, S ;

KUMAGAI, T ;

HABATA, Y ;

SATO, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (08) :1497-1505

[2] CYCLOTRIVERATRYLENE CROWN ETHERS - METAL-ION EXTRACTION AND TRANSPORT ABILITIES THROUGH ORGANIC MEMBRANE [J].

AKABORI, S ;

TAKEDA, M ;

KAWAKAMI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (04) :1413-1415

[3]

BRINK M, 1965, ACTA U LUND 2, V16, P1

[4]

CANCEIL J, 1989, ANGEW CHEM INT EDIT, V29, P1246

[5] ANALYTICAL OPTICAL RESOLUTION OF BROMOCHLOROFLUOROMETHANE BY ENANTIOSELECTIVE INCLUSION INTO A TAILOR-MADE CRYPTOPHANE AND DETERMINATION OF ITS MAXIMUM ROTATION [J].

CANCEILL, J ;

LACOMBE, L ;

COLLET, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) :6993-6996

[6] NEW CRYPTOPHANE FORMING UNUSUALLY STABLE INCLUSION COMPLEXES WITH NEUTRAL GUESTS IN A LIPOPHILIC SOLVENT [J].

CANCEILL, J ;

LACOMBE, L ;

COLLET, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) :4230-4232

[7] A NEW BIS-CYCLOTRIBENZYL CAVITAND CAPABLE OF SELECTIVE INCLUSION OF NEUTRAL MOLECULES IN SOLUTION - CRYSTAL-STRUCTURE OF ITS CH2CL2 CAVITATE [J].

CANCEILL, J ;

CESARIO, M ;

COLLET, A ;

GUILHEM, J ;

PASCARD, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (06) :361-363

[8] OPTICAL-ACTIVITY DUE TO ISOTOPIC-SUBSTITUTION - SYNTHESIS, STEREOCHEMISTRY, AND CIRCULAR-DICHROISM OF (+)-[2,7,12-H-2(3)]CYCLOTRIBENZYLENE AND (-)-[2,7,12-H-2(3)]CYCLOTRIBENZYLENE [J].

CANCEILL, J ;

COLLET, A ;

GOTTARELLI, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (20) :5997-6003

[9] 2-STEP SYNTHESIS OF D3 AND C3H CRYPTOPHANES [J].

CANCEILL, J ;

COLLET, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (09) :582-584

[10] CYCLOTRIVERATRYLENES AND CRYPTOPHANES [J].

COLLET, A .

TETRAHEDRON, 1987, 43 (24) :5725-5759

← 1 2 3 →