A new class of macrocycle capable of binding exogenous metals:: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1,4,8,11-tetraazacyclotetradecane-2,3-dione [exoO2]cyclam

被引:62
作者
Cronin, L [1 ]
Mount, AR [1 ]
Parsons, S [1 ]
Robertson, N [1 ]
机构
[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 12期
关键词
D O I
10.1039/a902792k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Synthesis of the new macrocycle 1,4,8,11-tetraazacyclo-tetradecane-2,3-dione [exoO(2)]cyclam and its complexation with copper(II) ion via the tetraaza groups and linked together through a copper(II) ion coordinated to the exo-cis oxygen donors of each macrocycle.
引用
收藏
页码:1925 / 1927
页数:3
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