SERS of 1,8-diaminonaphthalene on gold, silver and copper electrodes - Polymerisation and complexes formed with the electrode material

被引：69

作者：

Palys, BJ ^{[1
]}

Bukowska, J ^{[1
]}

Jackowska, K ^{[1
]}

机构：

[1] UNIV WARSAW,DEPT CHEM,PL-02093 WARSAW,POLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 428卷 / 1-2期

关键词：

1,8-diaminonaphthalene; electro-oxidation; electroactive polymers; SERS;

D O I：

10.1016/S0022-0728(97)00029-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Oxidation of 1,8-diaminonaphthalene (1,8DAN) on gold, silver and copper electrodes has been studied by SERS spectra. SERS results have been compared with Raman spectra of poly-1,8DAN thin films deposited on the platinum support. Oxidation of I,8DAN on gold and silver electrodes leads to polymerisation. The pretreatment of the silver electrode influences the polymerisation: exposing the silver electrode to day light during the ORC procedure encourages growth of the polymer layer. In the case of a copper electrode the Cu2(+)-(1,8DAN)(n) complex is formed. (C) 1997 Elsevier Science S.A.

引用

页码：19 / 24

页数：6

共 10 条

[1] ELECTROPOLYMERIZATION OF 1,5-DIAMINONAPHTHALENE IN ACETONITRILE AND IN AQUEOUS-SOLUTION [J].