Separation of ionic and solvent transport during charge compensation processes in electroactive polymers by a.c. electrogravimetry

被引：34

作者：

Gabrielli, C

Keddam, M

Perrot, H

Pham, MC

Torresi, R

机构：

[1] Univ Paris 06, CNRS, UPR Phys Liquides & Electrochim 15, F-75252 Paris 05, France

[2] Univ Paris 07, ITODYS, F-75252 Paris, France

[3] Univ Sao Paulo, Dept Quim Fis, BR-13560 Sao Carlos, Brazil

来源：

ELECTROCHIMICA ACTA | 1999年 / 44卷 / 24期

关键词：

electrochemical impedance; electrogravimetry; redox polymers; conducting polymers; ionic insertion;

D O I：

10.1016/S0013-4686(99)00136-X

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Simultaneous measurement of the faradaic impedance and electrogravimetric transfer function during the redox reactions of a polymer in HClO4 allows anions, cations and solvent contributions to the charge compensation processes to be separated and their insertion/expulsion rate to be evaluated. A model of the transport processes in the polymer and the charge transfer kinetics of the ions and solvent at the polymer/solution interface is proposed. For the polymers and experimental conditions investigated, it was shown that the anions are generally inserted and the solvent generally expelled. Concerning the cations or species related to cations. e.g. hydronium ions, they can be either inserted or expelled. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4217 / 4225

页数：9

共 32 条

[1] Sulphonated polyaniline (SPAN) films as cation insertion electrodes for battery applications - Part II: Exchange of mobile species in aqueous and non-aqueous solutions
Barbero, C
Miras, MC
Kotz, R
Haas, O
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 437 (1-2): : 191 - 198
[2] AN ELECTROCHEMICAL QUARTZ-CRYSTAL MICROBALANCE STUDY OF LITHIUM INSERTION INTO THIN-FILMS OF TUNGSTEN TRIOXIDE .2. EXPERIMENTAL RESULTS AND COMPARISON WITH MODEL-CALCULATIONS
BOHNKE, O
VUILLEMIN, B
GABRIELLI, C
KEDDAM, M
PERROT, H
[J]. ELECTROCHIMICA ACTA, 1995, 40 (17) : 2765 - 2773
[3] AN ELECTROCHEMICAL QUARTZ-CRYSTAL MICROBALANCE STUDY OF LITHIUM INSERTION INTO THIN-FILMS OF TUNGSTEN TRIOXIDE .1. MODELING OF THE IONIC INSERTION MECHANISM
BOHNKE, O
VUILLEMIN, B
GABRIELLI, C
KEDDAM, M
PERROT, H
TAKENOUTI, H
TORRESI, R
[J]. ELECTROCHIMICA ACTA, 1995, 40 (17) : 2755 - 2764
[4] STUDY OF ELECTROCHEMICAL PHASE FORMATION AND DISSOLUTION BY AC-QUARTZ ELECTROGRAVIMETRY
BOURKANE, S
GABRIELLI, C
KEDDAM, M
[J]. ELECTROCHIMICA ACTA, 1989, 34 (08) : 1081 - 1092
[5] INVESTIGATION OF GOLD OXIDATION IN SULFURIC MEDIUM .2. ELECTROGRAVIMETRIC TRANSFER-FUNCTION TECHNIQUE
BOURKANE, S
GABRIELLI, C
KEDDAM, M
[J]. ELECTROCHIMICA ACTA, 1993, 38 (14) : 1827 - 1835
[6] INVESTIGATION OF GOLD OXIDATION IN SULFURIC MEDIUM .1. ELECTROCHEMICAL IMPEDANCE TECHNIQUES
BOURKANE, S
GABRIELLE, C
HUET, F
KEDDAM, M
[J]. ELECTROCHIMICA ACTA, 1993, 38 (07) : 1023 - 1028
[7] CONSEQUENCES OF THERMODYNAMIC RESTRAINTS ON SOLVENT AND ION TRANSFER DURING REDOX SWITCHING OF ELECTROACTIVE POLYMERS
BRUCKENSTEIN, S
HILLMAN, AR
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (17) : 4837 - 4839
[8] CORDOBATORRESI S, 1990, J ELECTROANAL CHEM, V290, P261
[9] COMPARISON OF THE AC-IMPEDANCE OF CONDUCTING POLYMER-FILMS STUDIED AS ELECTRODE-SUPPORTED AND FREESTANDING MEMBRANES
DESLOUIS, C
MUSIANI, MM
TRIBOLLET, B
VOROTYNTSEV, MA
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) : 1902 - 1908
[10] Free-standing membranes for the study of electrochemical reactions occurring at conducting polymer/electrolyte interfaces
Deslouis, C
Musiani, MM
Tribollet, B
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (21) : 8994 - 8999

← 1 2 3 4 →