Photo-induced metastable linkage isomers of ruthenium nitrosyl porphyrins

被引：58

作者：

Fomitchev, DV ^{[1
]}

Coppens, P

Li, TS

Bagley, KA

Chen, L

Richter-Addo, GB

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

[2] SUNY Coll Buffalo, Dept Chem, Buffalo, NY 14222 USA

[3] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 19期

关键词：

D O I：

10.1039/a905285b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

IR spectroscopic results, combined with earlier crystallographic and spectroscopic evidence on Fe and Ru nitrosyl complexes, indicate that metastable eta(1)-O and eta(2)-NO linkage isomers are formed on low-temperature irradiation of the nitrosyl metalloporphyrins (OEP)Ru(NO)L (L = O-i-C5H11, SCH2CF3); the new compounds are stable at low temperature, but revert to the ground state on warming.

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页码：2013 / 2014

页数：2

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