Stable isotopic compositions of carbon monoxide from biomass burning experiments

被引：24

作者：

Kato, S

Akimoto, H

Röckmann, T

Bräunlich, M

Brenninkmeijer, CAM

机构：

[1] Univ Tokyo, Adv Sci & Technol Res Ctr, Meguro Ku, Tokyo 1538904, Japan

[2] Max Planck Inst Chem, Div Atmospher Chem, D-55128 Mainz, Germany

来源：

ATMOSPHERIC ENVIRONMENT | 1999年 / 33卷 / 27期

关键词：

isotopic fractionation; atmospheric chemistry; C-13; O-18; CO;

D O I：

10.1016/S1352-2310(99)00243-5

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The stable isotope composition of carbon monoxide (CO) from burning plants was measured to provide insight about isotopic compositions of CO from biomass burning. Both C-13/C-12 and O-18/O-16 ratios of CO decreased with the time from ignition and those trends were not depending on the plant species. delta(13)C values of produced CO were heavier (0.6-3.6 parts per thousand V-PDB) than those of the burned plants during flaming stage, but they became lighter (-2.1- -6.8 parts per thousand V- PDB) during smoldering stage. Because CO production is enhanced in smoldering stage, average isotopic compositions of CO from biomass burning would be lighter than those of burned plants. For atmospheric model calculations on CO isotopes, isotopic fractionation of CO from biomass burning should be considered. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：4357 / 4362

页数：6

相关论文

共 23 条

[1] Isotope analysis based source identification for atmospheric CH4 and CO sampled across Russia using the Trans-Siberian railroad [J].

Bergamaschi, P ;

Brenninkmeijer, CAM ;

Hahn, M ;

Rockmann, T ;

Scharffe, DH ;

Crutzen, PJ ;

Elansky, NF ;

Belikov, IB ;

Trivett, NBA ;

Worthy, DEJ .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D7) :8227-8235

[2] ROBUST, HIGH-EFFICIENCY, HIGH-CAPACITY CRYOGENIC TRAP [J].

BRENNINKMEIJER, CAM .

ANALYTICAL CHEMISTRY, 1991, 63 (11) :1182-1184

[3] Principal factors determining the O-18/O-16 ratio of atmospheric CO as derived from observations in the southern hemispheric troposphere and lowermost stratosphere [J].

Brenninkmeijer, CAM ;

Rockmann, T .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D21) :25477-25485

[4] The C-13, C-14 and O-18 isotopic composition of CO, CH4, and CO2 in the higher southern latitudes lower stratosphere [J].

Brenninkmeijer, CAM ;

Lowe, DC ;

Manning, MR ;

Sparks, RJ ;

vanVelthoven, PFJ .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1995, 100 (D12) :26163-26172

[5] MEASUREMENT OF THE ABUNDANCE OF (CO)-C-14 IN THE ATMOSPHERE AND THE C-13 C-12 AND O-18 O-16 RATIO OF ATMOSPHERIC CO WITH APPLICATIONS IN NEW-ZEALAND AND ANTARCTICA [J].

BRENNINKMEIJER, CAM .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1993, 98 (D6) :10595-10614

[6] A large (CO)-C-13 deficit in the lower Antarctic stratosphere due to ''ozone hole'' chemistry .1. Observations [J].

Brenninkmeijer, CAM ;

Muller, R ;

Crutzen, PJ ;

Lowe, DC ;

Manning, MR ;

Sparks, RJ ;

vanVelthoven, PFJ .

GEOPHYSICAL RESEARCH LETTERS, 1996, 23 (16) :2125-2128

[7]

BRENNINKMEIJER CAM, 1983, THESIS U GRONINGEN T

[8] CARBON KINETIC ISOTOPE EFFECT IN THE OXIDATION OF METHANE BY THE HYDROXYL RADICAL [J].

CANTRELL, CA ;

SHETTER, RE ;

MCDANIEL, AH ;

CALVERT, JG ;

DAVIDSON, JA ;

LOWE, DC ;

TYLER, SC ;

CICERONE, RJ ;

GREENBERG, JP .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1990, 95 (D13) :22455-22462

[9] Carbon 13 composition of tropospheric CO in Brazil: A model scenario during the biomass burn season [J].

Conny, JM ;

Verkouteren, RM ;

Currie, LA .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D9) :10683-10693

[10] BIOMASS BURNING IN THE TROPICS - IMPACT ON ATMOSPHERIC CHEMISTRY AND BIOGEOCHEMICAL CYCLES [J].

CRUTZEN, PJ ;

ANDREAE, MO .

SCIENCE, 1990, 250 (4988) :1669-1678