Metal mediated solvent free synthesis of homoallylic alcohols

被引：24

作者：

Andrews, PC ^{[1
]}

Peatt, AC

Raston, CL

机构：

[1] Monash Univ, Sch Chem, Ctr Green Chem, Clayton, Vic 3800, Australia

[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

GREEN CHEMISTRY | 2001年 / 3卷 / 06期

关键词：

D O I：

10.1039/b108188h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In, Bi, Cu and Zn metals mediate the allylation of various carbonyl compounds under solvent free conditions. Controlling the exothermic nature of these reactions, to prevent decomposition of starting materials, results in good to excellent yields of the corresponding homoallylic alcohols.

引用

页码：313 / 315

页数：3

共 27 条

[1]

Anastas P. T., 1998, GREEN CHEM THEORY PR

[2] Clay-catalysed solventless synthesis of trans-chalcones [J].

Ballini, R ;

Bosica, G ;

Maggi, R ;

Ricciutelli, M ;

Righi, P ;

Sartori, G ;

Sartorio, R .

GREEN CHEMISTRY, 2001, 3 (04) :178-180

[3] Recent advances in solventless organic reactions: towards benign synthesis with remarkable versatility [J].

Cave, GWV ;

Raston, CL ;

Scott, JL .

CHEMICAL COMMUNICATIONS, 2001, (21) :2159-2169

[4] Toward benign syntheses of pyridines involving sequential solvent free aldol and Michael addition reactions [J].

Cave, GWV ;

Raston, CL .

CHEMICAL COMMUNICATIONS, 2000, (22) :2199-2200

[5] Organometallic reactions in aqueous media. The nature of the organotin intermediate in the tin-mediated allylation of carbonyl compounds [J].

Chan, TH ;

Yang, Y ;

Li, CJ .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (12) :4452-4455

[6] Organometallic reactions in aqueous media. Indium-mediated allylation of sulfonimines [J].

Chan, TH ;

Lu, WS .

TETRAHEDRON LETTERS, 1998, 39 (47) :8605-8608

[7] Indium-mediated organometallic reactions in aqueous media: The nature of the allylindium intermediate [J].

Chan, TH ;

Yang, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (13) :3228-3229

[8] 1993 RU-LEMIEUX-AWARD-LECTURE - ORGANOMETALLIC-TYPE REACTIONS IN AQUEOUS-MEDIA - A NEW CHALLENGE IN ORGANIC-SYNTHESIS [J].

CHAN, TH ;

LI, CJ ;

LEE, MC ;

WEI, ZY .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1994, 72 (05) :1181-1192

[9]

Cotton F.A., 1988, Advanced Inorganic Chemistry

[10] New directions in inorganic and metal-organic coordination chemistry in supercritical fluids [J].

Darr, JA ;

Poliakoff, M .

CHEMICAL REVIEWS, 1999, 99 (02) :495-541

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