Optimization of Orange-Emitting Electrophosphorescent Copolymers for Organic Light-Emitting Diodes

被引:71
作者
Haldi, Andreas [1 ]
Kimyonok, Alpay [1 ]
Domercq, Benoit [1 ]
Hayden, Lauren E. [1 ]
Jones, Simon C. [1 ]
Marder, Seth R. [2 ]
Weck, Marcus [2 ]
Kippelen, Bernard [2 ]
机构
[1] Georgia Inst Technol, Sch Chem & Biochem, Ctr Organ Photon, Atlanta, GA 30332 USA
[2] Georgia Inst Technol, Sch Elect & Comp Engn, COPE, Atlanta, GA 30332 USA
基金
美国国家科学基金会;
关键词
D O I
10.1002/adfm.200800446
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Orange-emitting phosphorescent copolymers containing iridium complexes and bis(carbazolyl)fluorene groups in their side chains are employed as the emissive layer in multilayer organic light-emitting diodes (OLEDs). The efficiency of the OLED devices is optimized by varying characteristics of the copolymers: the molecular weight, the iridium loading level, and the nature and length of the linker between the side chains and the polymer backbone. A maximum efficiency of 4.9 +/- 0.4%, 8.8 +/- 0.7 cd A(-1) at 100 cd m(-2) is achieved with an optimized copolymer.
引用
收藏
页码:3056 / 3062
页数:7
相关论文
共 44 条
[1]   Nearly 100% internal phosphorescence efficiency in an organic light-emitting device [J].
Adachi, C ;
Baldo, MA ;
Thompson, ME ;
Forrest, SR .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5048-5051
[2]   Transient analysis of organic electrophosphorescence. II. Transient analysis of triplet-triplet annihilation [J].
Baldo, MA ;
Adachi, C ;
Forrest, SR .
PHYSICAL REVIEW B, 2000, 62 (16) :10967-10977
[3]   Very high-efficiency green organic light-emitting devices based on electrophosphorescence [J].
Baldo, MA ;
Lamansky, S ;
Burrows, PE ;
Thompson, ME ;
Forrest, SR .
APPLIED PHYSICS LETTERS, 1999, 75 (01) :4-6
[4]   New triarylamine-containing polymers as hole transport materials in organic light-emitting diodes: Effect of polymer structure and cross-linking on device characteristics [J].
Bellmann, E ;
Shaheen, SE ;
Thayumanavan, S ;
Barlow, S ;
Grubbs, RH ;
Marder, SR ;
Kippelen, B ;
Peyghambarian, N .
CHEMISTRY OF MATERIALS, 1998, 10 (06) :1668-1676
[5]   HOLE TRANSPORT IN 1,1-BIS(DI-4-TOLYLAMINOPHENYL)CYCLOHEXANE [J].
BORSENBERGER, PM ;
PAUTMEIER, L ;
RICHERT, R ;
BASSLER, H .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :8276-8281
[6]   Phosphorescent side-chain functionalized poly(norbornene)s containing iridium complexes [J].
Carlise, JR ;
Wang, XY ;
Weck, M .
MACROMOLECULES, 2005, 38 (22) :9000-9008
[7]   Triplet exciton confinement in phosphorescent polymer light-emitting diodes [J].
Chen, FC ;
He, GF ;
Yang, Y .
APPLIED PHYSICS LETTERS, 2003, 82 (07) :1006-1008
[8]   Synthesis and characterization of polymerizable phosphorescent platinum(II) complexes for solution-processible organic light-emitting diodes [J].
Cho, Jian-Yang ;
Domercq, Benoit ;
Barlow, Stephen ;
Suponitsky, Kyrill Yu. ;
Li, Jennifer ;
Timofeeva, Tatiana V. ;
Jones, Simon C. ;
Hayden, Lauren E. ;
Kimyonok, Alpay ;
South, Clinton R. ;
Weck, Marcus ;
Kippelen, Bernard ;
Marder, Seth R. .
ORGANOMETALLICS, 2007, 26 (19) :4816-4829
[9]   Living radical polymerization of bipolar transport materials for highly efficient light emitting diodes [J].
Deng, L ;
Furuta, PT ;
Garon, S ;
Li, J ;
Kavulak, D ;
Thompson, ME ;
Fréchet, JMJ .
CHEMISTRY OF MATERIALS, 2006, 18 (02) :386-395
[10]   Photo-patternable hole-transport polymers for organic light-emitting diodes [J].
Domercq, B ;
Hreha, RD ;
Zhang, YD ;
Larribeau, N ;
Haddock, JN ;
Schultz, C ;
Marder, SR ;
Kippelen, B .
CHEMISTRY OF MATERIALS, 2003, 15 (07) :1491-1496