Use of biofuels to produce hydrogen (reformation processes)

被引：254

作者：

Ramirez de la Piscina, Pilar ^{[1
,2
]}

Homs, Narcis ^{[1
,2
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain

[2] Univ Barcelona, Inst Nanociencia & Nanotecnol, E-08028 Barcelona, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2008年 / 37卷 / 11期

关键词：

D O I：

10.1039/b712181b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review deals with the catalytic reformation of ethanol and glycerol to produce hydrogen that can be used as an energy carrier in a fuel cell. Both the worldwide production of ethanol in large amounts to be used as a biofuel and that of glycerol as a by-product in biodiesel manufacture are presented. The catalytic reformation processes of both ethanol and glycerol are contemplated, including thermodynamic and kinetic aspects. Catalysts are analyzed as a function of operation conditions, selectivity and stability.

引用

收藏

页码：2459 / 2467

页数：9

相关论文

共 39 条

[21] Thermodynamic analysis of hydrogen production from oxidative steam reforming of ethanol [J].

Liu, Shuo ;

Zhang, Ke ;

Fang, Lining ;

Li, Yongdan .

ENERGY & FUELS, 2008, 22 (02) :1365-1370

[22] Direct production of hydrogen from ethanolic aqueous solutions over oxide catalysts [J].

Llorca, J ;

de la Piscina, PR ;

Sales, J ;

Homs, N .

CHEMICAL COMMUNICATIONS, 2001, (07) :641-642

[23] Thermodynamic study on hydrogen generation from different glycerol reforming processes [J].

Luo, Nianjun ;

Zhao, Xun ;

Cao, Fahai ;

Xiao, Tiancun ;

Fang, Dingye .

ENERGY & FUELS, 2007, 21 (06) :3505-3512

[24] Oxygenate reaction pathways on transition metal surfaces [J].

Mavrikakis, M ;

Barteau, MA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 131 (1-3) :135-147

[25] Hydrogen production reactions from carbon feedstocks:: Fossils fuels and biomass [J].

Navarro, R. M. ;

Pena, M. A. ;

Fierro, J. L. G. .

CHEMICAL REVIEWS, 2007, 107 (10) :3952-3991

[26] Production of hydrogen by oxidative reforming of ethanol over Pt catalysts supported on Al2O3 modified with Ce and La [J].

Navarro, RM ;

Alvarez-Galván, MC ;

Sánchez-Sánchez, MC ;

Rosa, F ;

Fierro, JLG .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 55 (04) :229-241

[27]

NICHOLS NN, 2006, ALCOHOLIC FUELS, pCH4

[28] Oxidative steam-reforming of ethanol over Co/SiO2, Co-Ru/SiO2 and Co-Ru/SiO2 catalysts:: Catalytic behavior and deactivation/regeneration processes [J].

Pereira, Evandro B. ;

Homs, Narcis ;

Marti, Salvador ;

Fierro, J. L. G. ;

de la Piscina, Pilar Ramirez .

JOURNAL OF CATALYSIS, 2008, 257 (01) :206-214

[29] Renewable hydrogen: carbon formation on Ni and Ru catalysts during ethanol steam-reforming [J].

Rass-Hansen, Jeppe ;

Christensen, Claus Hviid ;

Sehested, Jens ;

Helveg, Stig ;

Rostrup-Nielsen, Jens R. ;

Dahl, Soren .

GREEN CHEMISTRY, 2007, 9 (09) :1016-1021

[30] Catalyst deactivation and regeneration in low temperature ethanol steam reforming with Rh/CeO2-ZrO2 catalysts [J].

Roh, Hyun-Seog ;

Platon, Alexandru ;

Wang, Yong ;

King, David L. .

CATALYSIS LETTERS, 2006, 110 (1-2) :1-6

← 1 2 3 4 →