On the species involved in the vaporization of imidazolium ionic liquids in a steam-distillation-like process

被引：82

作者：

Neto, Brenno A. DaSilveira

Santos, Leonardo S.

Nachtigall, Fabiane M.

Eberlin, Marcos N. ^{[1
]}

Dupont, Jairton

机构：

[1] Univ Fed Rio Grande do Sul, Inst Chem, Lab Mol Catalysis, BR-91501970 Porto Alegre, RS, Brazil

[2] Univ Estadual Campinas, Thomson Mass Sepct Lab, Inst Chem, BR-13083970 Campinas, SP, Brazil

[3] Talca Univ, Chem Inst Nat Resources, Norte 685, Talca, Chile

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 43期

关键词：

distillation; imidazolium; ionic liquids; mass spectrometry;

D O I：

10.1002/anie.200602219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Steaming ahead: The nonvolatility of ionic liquids is challenged further. Imidazolium(lm)-based ionic liquids composed of supramolecular structures in the condensed phase (see scheme) vaporize at ambient pressure from heated (100-600°C) solvent droplets as neutral clusters of the type Im nAn. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7251 / 7254

页数：4

共 28 条

[1] Evidence for the clustering of substituted imidazolium salts via hydrogen bonding under the conditions of fast atom bombardment mass spectrometry [J].

AbdulSada, AK ;

Elaiwi, AE ;

Greenway, AM ;

Seddon, KR .

EUROPEAN MASS SPECTROMETRY, 1997, 3 (03) :245-247

[2] Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures [J].

Antonietti, M ;

Kuang, DB ;

Smarsly, B ;

Yong, Z .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :4988-4992

[3]

Antonietti M, 2004, ANGEW CHEM, V116, P5096

[4]

Armarego W.L.F., 1997, PURIFICATION LAB CHE

[5] From fundamentals to applications: recent developments in atmospheric pressure photoionization mass spectrometry [J].

Bos, SJ ;

van Leeuwen, SM ;

Karst, U .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2006, 384 (01) :85-99

[6] A simple and practical method for the preparation and purity determination of halide-free imidazolium ionic liquids [J].

Cassol, CC ;

Ebeling, G ;

Ferrera, B ;

Dupont, J .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) :243-248

[7]

Chen H, 2006, ANGEW CHEM, V118, P3738

[8] Thermal production and reactions of organic ions at atmospheric pressure [J].

Chen, Hao ;

Zheng Ouyang ;

Cooks, R. Graham .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (22) :3656-3660

[9] Identification of 1,3-dialkylimidazolium salt supramolecular aggregates in solution [J].

Consorti, CS ;

Suarez, PAZ ;

de Souza, RF ;

Burrow, RA ;

Farrar, DH ;

Lough, AJ ;

Loh, W ;

da Silva, LHM ;

Dupont, J .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (10) :4341-4349

[10] On the noninnocent nature of 1,3-dialkylimidazolium ionic liquids [J].

Dupont, J ;

Spencer, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (40) :5296-5297

← 1 2 3 →