Acetalization of polyvinyl alcohol with furfural

被引:26
作者
Gousse, C [1 ]
Gandini, A [1 ]
机构
[1] INST NATL POLYTECH GRENOBLE,ECOLE FRANCAISE PAPETERIE & IND GRAPH,F-38402 ST MARTIN DHER,FRANCE
关键词
D O I
10.1016/S0014-3057(96)00234-0
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The condensation reaction of 2-furaldehyde (Fu) with poly(vinyl alcohol) (PVA) to give the corresponding acetal was studied in detail. In order to assess in a satisfactory manner the ensuing modified polymers in quantitative terms, a model reaction involving Fu and pentaerythritol was investigated and the bis-acetal obtained submitted to a thorough characterization. Two solvents were used for the polymer modification, viz. water and DMSO. The maximum degree of substitution attained was about 60% in both media. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:667 / 671
页数:5
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