Monodisperse nanoparticle synthesis by an atmospheric pressure plasma process: An example of a visible light photocatalyst

被引:16
作者
Bai, HL
Chen, CC
Lin, CS
Den, W
Chang, CL
机构
[1] Natl Chiao Tung Univ, Inst Environm Engn, Hsinchu, Taiwan
[2] Tunghai Univ, Dept Environm Sci, Taichung 40704, Taiwan
[3] Yuanpei Inst Sci & Technol, Dept Environm Engn & Hlth, Hsinchu, Taiwan
关键词
D O I
10.1021/ie049815x
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
An atmospheric pressure plasma-enhanced nanoparticle synthesis (APPENS) process was proposed to produce a titania-based visible light photocatalyst. The titanium tetraisopropoxide (TTIP) precursor was vaporized with a N-2 carrier gas and entered a nonthermal AC plasma system. The N-2 gas was dissociated into N atoms by the plasma energy, and then they were doped into the precursor vapors. The produced TiO2-xNx nanoparticles were highly uniform and adjustable in size. The titania-based particle sizes ranged from 25 to 40 nm, and they depended on the precursor ratio of TTIP/H-2O. In addition to producing the photocatalytic particles, the APPENS process has a potential application as a continuous-flow nanosize monodisperse aerosol generator.
引用
收藏
页码:7200 / 7203
页数:4
相关论文
共 26 条
[1]   Role of synthesis method and particle size of nanostructured TiO2 on its photoactivity [J].
Almquist, CB ;
Biswas, P .
JOURNAL OF CATALYSIS, 2002, 212 (02) :145-156
[2]   The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation [J].
Anpo, M ;
Takeuchi, M .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :505-516
[3]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[4]   Enhanced nitrogen doping in TiO2 nanoparticles [J].
Burda, C ;
Lou, YB ;
Chen, XB ;
Samia, ACS ;
Stout, J ;
Gole, JL .
NANO LETTERS, 2003, 3 (08) :1049-1051
[5]   Destruction and removal of toluene and MEK from gas streams with silent discharge plasmas [J].
Chang, MB ;
Chang, CC .
AICHE JOURNAL, 1997, 43 (05) :1325-1330
[6]   Experimental study on ozone synthesis via dielectric barrier discharges [J].
Chang, MB ;
Wu, SJ .
OZONE-SCIENCE & ENGINEERING, 1997, 19 (03) :241-254
[7]   THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].
CHOI, WY ;
TERMIN, A ;
HOFFMANN, MR .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (51) :13669-13679
[8]  
Friedlander S. K., 2000, Smoke, Dust, and Haze: Fundamentals of Aerosol Dynamics, V2nd
[9]   Particle generation and thin film surface morphology in the tetraethylorthosilicate/oxygen plasma enhanced chemical vapor deposition process [J].
Fujimoto, T ;
Okuyama, K ;
Shimada, M ;
Fujishige, Y ;
Adachi, M ;
Matsui, I .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (05) :3047-3052
[10]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+