Kinetic modeling of the hydrogenation of 1,5,9-cyclododecatriene on Pd/Al2O3 catalyst including isomerization

被引：16

作者：

Benaissa, M ^{[1
]}

LeRoux, GC ^{[1
]}

Joulia, X ^{[1
]}

Chaudhari, RV ^{[1
]}

Delmas, H ^{[1
]}

机构：

[1] INPT,ENSIGC,UMR 5503 CNRS,LAB GENIE CHIM,F-31078 TOULOUSE,FRANCE

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1996年 / 35卷 / 07期

关键词：

D O I：

10.1021/ie960011u

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetic modeling of the hydrogenation of 1,5,9-cyclododecatriene has been studied using a Pd/Al2O3 catalyst in a slurry reactor on the basis of a complete isomers analysis. A reaction scheme involving multistep hydrogenation and reversible isomerization reactions has been considered and a kinetic model of Langmuir-Hinshelwood type proposed. The kinetic parameters were estimated from experimental batch slurry reactor data. The model predictions of cyclododecene selectivity at different pressures agree well with the experimental data.

引用

页码：2091 / 2095

页数：5

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