A bis(1,2,3-dithiazole) charge transfer salt with 2: 1 stoichiometry; inhibition of association and generation of slipped π-stacks

被引:5
作者
Barclay, Tosha M. [2 ]
Cordes, A. Wallace [2 ]
Mingie, James R. [1 ]
Oakley, Richard T. [1 ]
Preuss, Kathryn E. [1 ]
机构
[1] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
[2] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA
来源
CRYSTENGCOMM | 2000年 / 15期
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1039/b004239k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first example of a charge transfer salt of a benzo-bridged bis(1,2,3-dithiazole) with 2 : 1 stoichiometry is reported; the steric bulk of the chlorines at the 3,6-positions of the benzene ring induces slipped pi-stacks of dimer radical cations.
引用
收藏
页码:89 / 91
页数:3
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