Novel environmental control chamber for FT-Raman spectroscopy: Study of in situ phase change of sulfur

被引：16

作者：

Edwards, HGM

Farwell, DW

Turner, JMC

Williams, AC

机构：

[1] Chemistry and Chemical Technology, University of Bradford

[2] Dept. of Pharmaceutical Technology, School of Pharmacy, University of Bradford

来源：

APPLIED SPECTROSCOPY | 1997年 / 51卷 / 01期

关键词：

FT-Raman spectroscopy; phase change; environmental control; sulfur;

D O I：

10.1366/0003702971938830

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The adaptation and construction of an environmental chamber suitable for FT-Raman spectroscopy is described for the recording of Raman spectra of specimens at temperatures from 25 to 125 degrees C while exposed to different controlled synthetic atmospheric conditions. Test spectra were obtained from sulfur to illustrate the stability and applications of the system. The alpha rhombic/beta monoclinic phase change in sulfur was monitored as a function of time, and bands sensitive to this phase change have been identified.

引用

页码：101 / 107

页数：7

共 20 条

[1] LOW TEMPERATURE RAMAN SPECTRUM OF RHOMBIC SULFUR [J].