Liquid-liquid equilibria of alkane (C10-C14) plus butylbenzene plus sulfolane

被引：11

作者：

Kao, CF ^{[1
]}

Lin, WC ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 70101, Taiwan

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1999年 / 44卷 / 04期

关键词：

D O I：

10.1021/je990020k

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Equilibrium tie line data have been determined at 323.15 K, 348.15 K, and 373.15 K for the ternary liquid-liquid equilibria (LLE) of three alkane + butylbenzene + sulfolane systems, where the alkanes studied are decane, undecane, and tetradecane. The relative mutual solubility of butylbenzene is higher in decane + sulfolane than in undecane + sulfolane or tetradecane + sulfolane mixtures. The tie line data were correlated with the UNIQUAC and NRTL models. The calculated values based on the UNIQUAC model were found to be better than those based on the NRTL model. The values of selectivity and the distribution coefficient were derived from the equilibrium data.

引用

页码：803 / 808

页数：6

共 12 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2] LIQUID LIQUID EQUILIBRIUM OF SULFOLANE BENZENE PENTANE AND SULFOLANE TOLUENE PENTANE [J].

CASSELL, GW ;

DURAL, N ;

HINES, AL .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1989, 28 (09) :1369-1374

[3] CORRELATION OF THE PHASE-EQUILIBRIUM DATA FOR THE HEPTANE TOLUENE SULFOLANE AND HEPTANE XYLENE SULFOLANE SYSTEMS [J].

CASSELL, GW ;

HASSAN, MM ;

HINES, AL .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (04) :434-438

[4] PHASE-EQUILIBRIA OF THE CYCLOHEXANE-TOLUENE-SULFOLANE AND HEXANE-TOLUENE-SULFOLANE TERNARY-SYSTEMS [J].

CASSELL, GW ;

HASSAN, MM ;

HINES, AL .

CHEMICAL ENGINEERING COMMUNICATIONS, 1989, 85 :233-243

[5] Liquid-liquid equilibria for the ternary systems sulfolane plus octane plus benzene, sulfolane plus octane plus toluene, and sulfolane plus octane plus p-xylene at elevated temperatures [J].

Lee, S ;

Kim, H .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (03) :358-361

[6] LIQUID-LIQUID EQUILIBRIA FOR THE TERNARY-SYSTEMS SULFOLANE PLUS OCTANE PLUS BENZENE, SULFOLANE PLUS OCTANE PLUS TOLUENE AND SULFOLANE PLUS OCTANE PLUS P-XYLENE [J].

LEE, SJ ;

KIM, HY .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (02) :499-503

[7] Liquid-liquid equilibria of the ternary mixtures with sulfolane at 303.15 K [J].

Letcher, TM ;

Redhi, GG ;

Radloff, SE ;

Domanska, U .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (03) :634-638

[8] LIQUID-LIQUID EQUILIBRIUM STUDIES ON HYDROCARBON (C10-C20)-SULFOLANE SYSTEMS [J].

MASOHAN, A ;

NANOTI, SM ;

SHARMA, KG ;

PURI, SN ;

GUPTA, P ;

RAWAT, BS .

FLUID PHASE EQUILIBRIA, 1990, 61 (1-2) :89-98

[9] LIQUID-LIQUID EQUILIBRIA FOR TERNARY-SYSTEMS .1. C6-ISOMERS + SULFOLANE + TOLUENE AT 298.15-K [J].

MONDRAGONGARDUNO, M ;

ROMEROMARTINEZ, A ;

TREJO, A .

FLUID PHASE EQUILIBRIA, 1991, 64 :291-303

[10]

RAWAT BS, 1976, J APPL CHEM BIOTECHN, V26, P425

← 1 2 →