Photochemical studies of iron-only hydrogenase model compounds

被引：20

作者：

Brown-McDonald, Jessie ^{[1
]}

Berg, Seth ^{[1
]}

Peralto, Marci ^{[1
]}

Works, Carmen ^{[1
]}

机构：

[1] Sonoma State Univ, Dept Chem, Rohnert Pk, CA 94928 USA

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 02期

关键词：

Photochemistry; Bioinorganic model compounds; Hydrogenase; CARBON-MONOXIDE; ACTIVE-SITE; FE; PROTONATION; BINDING; CYANIDE; FORM;

D O I：

10.1016/j.ica.2008.03.110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

FTIR studies of the photochemical reaction of Fe-2(SCH2CH2CH2S)(CO)(6) (1) in both acetonitrile and toluene are described. Photochemical and thermal reactivity was studied under air, nitrogen and CO, and results are consistent with the loss of CO from 1 upon photolysis and the generation of a solvento species in both coordinating and non-coordinating solvents. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：318 / 324

页数：7

共 23 条

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