Design of latent catalysts and their application to polymer synthesis

被引：71

作者：

Endo, T

Sanda, F

机构：

[1] Res. Lab. of Resources Utilization, Tokyo Institute of Technology, Midori-ku, Yokohama 226, Nagatsuta-cho

来源：

MACROMOLECULAR SYMPOSIA | 1996年 / 107卷

关键词：

D O I：

10.1002/masy.19961070123

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Design of latent catalysts such as benzyl sulfonium, benzyl ammonium, benzyl pyridinium, benzyl phosphonium, and hydrazinium salts, and their application to polymer synthesis have been described. They have been demonstrated as excellent thermal or photolatent catalysts for polymerizations of cyclic monomers such as epoxides, bicycle orthoesters, spiro orthocarbonates, and vinyl monomers such as styrene and vinyl ethers.

引用

页码：237 / 242

页数：6

共 26 条

[1]

CRIVELLO JV, 1981, DEV POLYM PHOTOCHEMI, pCH1

[2] THERMOINITIATED CATIONIC POLYMERIZATION OF BICYCLO ORTHO ESTER BY BENZYLSULFONIUM SALTS [J].