Regiochemistry of Wacker-type oxidation of vinyl group in the presence of neighboring oxygen functions .1.

被引：37

作者：

Pellissier, H

Michellys, PY

Santelli, M

机构：

[1] Lab. de Synthèse Organique, UPRESA au CNRS No 6009, Centre de St.-Jérôme, 13397 Marseille Cedex 20, Av. Esc. Normandie-Niemen

来源：

TETRAHEDRON | 1997年 / 53卷 / 22期

关键词：

D O I：

10.1016/S0040-4020(97)00449-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium(II) oxidation of (+/-)-17 alpha-vinyl-1,3,5(10)-gonatriene derivatives 1 bearing a lactonic bridge on the beta-face affords the expected acetyl derivatives. In contrast, when the lactonic bridge or a hydroxy group is present on the or-face (syn relationship), aldehydes resulting from an anti-Markovnikov hydroxypalladation are obtained in appreciable yields. (C) 1997 Elsevier Science Ltd.

引用

页码：7577 / 7586

页数：10

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