Correlation between Phase Transitions and Piezoelectric Properties in Lead-Free (K,Na,Li)NbO3-BaTiO3 Ceramics

被引:63
作者
Ahn, Cheol-Woo [1 ]
Park, Chee-Sung [1 ]
Viehland, Dwight [1 ]
Nahm, Sahn [2 ]
Kang, Dong-Heon [3 ]
Bae, Kyoo-Sik [3 ]
Priya, Shashank [1 ]
机构
[1] Virginia Tech, Ctr Energy Harvesting Mat & Syst, Blacksburg, VA 24061 USA
[2] Korea Univ, Dept Mat Sci & Engn, Seoul 136713, South Korea
[3] Suwon Univ, Dept Elect Mat Engn, Hwaseong 445743, Gyeonggi Do, South Korea
关键词
lead-free piezoelectric ceramics; phase transition; (K; Na; Li)NbO3-BaTiO3;
D O I
10.1143/JJAP.47.8880
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this manuscript, we report the polymorphic phase transitions, structural changes and piezoelectric properties of alkali niobate based lead-free ceramics. The phase transitions were characterized as a function of alkali niobate content at room temperature. The results clearly demonstrate that in this system high piezoelectric properties are achieved for a specific fraction of ferroelectric orthorhombic (O) and tetragonal (T) phases. Using Rietveld and powder diffraction analysis, a correlation was established among the piezoelectric response, the fraction of O and T phases, and KNN ratio for three different systems of (K,Na)NbO3-BaTiO3 (KNN-BT), KNN-LiNbO3 (LN), and (K,Na,Li)NbO3 (KNLN)-BT. [DOI: 10.1143/JJAP.47.8880]
引用
收藏
页码:8880 / 8883
页数:4
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