Bifacial dye-sensitized solar cells based on an ionic liquid electrolyte

被引:255
作者
Ito, Seigo [1 ,2 ]
Zakeeruddin, Shaik M. [2 ]
Comte, Pascal [2 ]
Liska, Paul [2 ]
Kuang, Daibin [2 ]
Graetzel, Michael [2 ]
机构
[1] Univ Hyogo, Grad Sch Engn, Dept Elect Engn & Comp Sci, Himeji, Hyogo 6712280, Japan
[2] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1038/nphoton.2008.224
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Solar energy is a promising solution to global energy-related problems because it is clean, inexhaustible and readily available. However, the deployment of conventional photovoltaic cells based on silicon is still limited by cost, so alternative, more cost-effective approaches are sought. Here we report a bifacial dye-sensitized solar cell structure that provides high photo-energy conversion efficiency (similar to 6%) for incident light striking its front or rear surfaces. The design comprises a highly stable ruthenium dye ( Z907Na) in combination with an ionic-liquid electrolyte and a porous TiO2 layer. The inclusion of a SiO2 layer between the electrodes to prevent generation of unwanted back current and optimization of the thickness of the TiO2 layer are responsible for the enhanced performance.
引用
收藏
页码:693 / 698
页数:6
相关论文
共 34 条
[1]   Ionic liquid-based electrolyte solidified with SiO2 nanoparticles for dye-sensitized solar cells [J].
Berginc, M. ;
Hocevar, M. ;
Krasovec, U. Opara ;
Hinsch, A. ;
Sastrawan, R. ;
Topic, M. .
THIN SOLID FILMS, 2008, 516 (14) :4645-4650
[2]   Self-organization of TiO2 nanoparticles in thin films [J].
Burnside, SD ;
Shklover, V ;
Barbe, C ;
Comte, P ;
Arendse, F ;
Brooks, K ;
Gratzel, M .
CHEMISTRY OF MATERIALS, 1998, 10 (09) :2419-2425
[3]   Dye-sensitized solar cells with conversion efficiency of 11.1% [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Watanabe, Yuki ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640
[4]   Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy [J].
Fabregat-Santiago, F ;
Bisquert, J ;
Garcia-Belmonte, G ;
Boschloo, G ;
Hagfeldt, A .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) :117-131
[5]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[6]   Novel cost-effective bifacial silicon solar cells with 19.4% front and 18.1% rear efficiency [J].
Hubner, A ;
Aberle, AG ;
Hezel, R .
APPLIED PHYSICS LETTERS, 1997, 70 (08) :1008-1010
[7]  
HUBNER A, C P 25 PVSC 31 17 MA, P489
[8]   Calibration of solar simulator for evaluation of dye-sensitized solar cells [J].
Ito, S ;
Matsui, H ;
Okada, K ;
Kusano, S ;
Kitamura, T ;
Wada, Y ;
Yanagida, S .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 82 (03) :421-429
[9]   Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% [J].
Ito, Seigo ;
Murakami, Takurou N. ;
Comte, Pascal ;
Liska, Paul ;
Graetzel, Carole ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
THIN SOLID FILMS, 2008, 516 (14) :4613-4619
[10]   Photovoltaic characterization of dye-sensitized solar cells:: Effect of device masking on conversion efficiency [J].
Ito, Seigo ;
Nazeeruddin, Md. Khaja ;
Liska, Paul ;
Comte, Pascal ;
Charvet, Raphael ;
Pechy, Peter ;
Jirousek, Marie ;
Kay, Andreas ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
PROGRESS IN PHOTOVOLTAICS, 2006, 14 (07) :589-601