A simple synthesis of oximes

被引：60

作者：

Damljanovic, I ^{[1
]}

Vukicevic, M ^{[1
]}

Vukicevic, RD ^{[1
]}

机构：

[1] Univ Kragujevac, Fac Sci, Dept Chem, Kragujevac 34000, Serbia Monteneg

来源：

MONATSHEFTE FUR CHEMIE | 2006年 / 137卷 / 03期

关键词：

solid-phase synthesis; hydroxyimination; aldehydes; ketones; oximes;

D O I：

10.1007/s00706-005-0427-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conversion of alicyclic and aliphatic carbonyl compounds as well as aromatic aldehydes into the corresponding oximes (up to quantitative yields) was achieved by simply grinding these reactants, hydroxylamine hydrochloride and sodium hydroxide without solvent. However, this procedure was unsuccessful in the case of aromatic ketones. In this case it was necessary to add silica gel as a catalyst.

引用

页码：301 / 305

页数：5

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