Stereocontrolled construction of the trans-tetrahydrofuran units in Annonaceous acetogenins

被引：23

作者：

Tian, SK ^{[1
]}

Wang, ZM ^{[1
]}

Jiang, JK ^{[1
]}

Shi, M ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Organomet Chem Lab, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 13期

关键词：

D O I：

10.1016/S0957-4166(99)00259-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An efficient synthetic method for the construction of trans-tetrahydrofuran (THF) unit from trans-1,5,9-decatriene was successfully developed by means of Sharpless AD reactions and oxidative cyclizations catalyzed by Co(modp)(2) under an oxygen atmosphere. Based on this new synthetic strategy, the trans-mono-THF unit, trans-bis-THF unit and trans-tris-THF unit in Annonaceous acetogenins were smoothly obtained. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2551 / 2562

页数：12

共 24 条

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