Hydrothermal synthesis of the blue potassium molybdenum bronze, K0.28MoO3

被引：12

作者：

Chin, K

Eda, K

Sotani, N ^{[1
]}

Whittingham, MS

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan

[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 164卷 / 01期

关键词：

hydrothermal reaction; blue bronze; alkali metal molybdenum bronze; low-temperature synthesis route; hydrated molybdenum bronze; hydrogen molybdenum bronze; mixed-valence compound; topotactical reaction;

D O I：

10.1006/jssc.2001.9450

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Blue potassium molybdenum bronze, K0.28MoO3, was prepared by hydrothermal heating hydrogen molybdenum bronze in KCl solution at 431 K. Hydrated molybdenum bronze was found formed as an intermediate during the conversion from hydrogen molybdenum bronze to blue bronze. The hydrothermal method proved itself an easy and effective for synthesis of mixed-valence compounds. (C) 2002 Elsevier Science (USA).

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页码：81 / 87

页数：7

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