An extreme water exchange rate: the europium(II) aqua ion

被引：27

作者：

Caravan, P ^{[1
]}

Merbach, AE ^{[1
]}

机构：

[1] UNIV LAUSANNE,INST CHIM MINERALE & ANALYT,BCH,CH-1015 LAUSANNE,SWITZERLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 22期

关键词：

D O I：

10.1039/a705971j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate of water exchange at the europium(II) aqua ion is measured by a combined variable-temperature O-17 NMR and EPR study; it is the fastest aqua exchange rate ever directly measured by magnetic resonance for a non Jahn-Teller ion, 3.5 x 10(9): s(-1) at 25 degrees C.

引用

页码：2147 / 2148

页数：2

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